Fabrication and Characterization of Iron oxide Nanoparticles and Iron oxide / Silicon Core/Shell In The Presence of Cationic Surfactants and Their Application To Improve The Degradation of Diazinon in Aqueous Solutions

Document Type : Full length research Paper

Authors

1 Department of Physics, Faculty of Science, Vali-e-Asr University of Kerman, Rafsanjan, Iran

2 Department of Physics, Faculty of Science, Vali-e-Asr University of Rafsanjan, Rafsanjan, Iran

3 Department of Plant Protection, Faculty of Agriculture, Vali-e-Asr University of Kerman, Rafsanjan, Iran

Abstract

In this paper, we used magnetic nanoparticles to improve the degradation of the diazinon. For this purpose, Iron oxide nanoparticles (Fe3O4) were synthesized by modified hydrothermal method. Subsequently, we used ultrasonic method and put a shell of the nanoparticles of the SiO2 on it. The obtained nanoparticles were then characterization using X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Vibrational Sampler Magnetic Meter (VSM), Scanning Electron Microscopy (SEM) and Transmission Electron Microscope (TEM), Which is x- ray diffraction pattern the inverse spinel structure of nanoparticles, The residual curve of the pure iron oxide sample showed 74 emu⁄(g )saturation magnetization and for the core-shell the saturation magnetization was 42emu⁄(g ). Result confirmed the paramagnetic properties. These nanoparticles exhibit superparamagnetic properties. The results of the transient electron microscope indicate the formation of this shell on iron oxide nanoparticles. Finally, these nanoparticles were used to degradation of diazinon in aqueous solution with different concentrations. Cetyltrimethylammonium bromide (CTAB) was used as an organic cationic surfactant to improve the degradation of diazinon.

Keywords

References

 
[1] A. Jafari, S. Farjami Shayesteh, M. Salouti, K. Boustani, Dependence of   structural phase transition and lattice strain of Fe3O4 nanoparticles on calcination temperature, Indian Journal of Physics. 77 (2014) 258-300.
[2] I. Kazeminezhad, S. Ahmadizadeh,  Effect of pH on the removal of copper ions from aqueous solutions using iron oxide nanoparticles and iron oxide/ hydroxyapatite nanocomposites, 3 5 (2013), 41-49
 [3] O. Salata, Applications of nanoparticles in biology and medicine, journal of Nanobiotechnology 288 (2004) 21-27.
[4] K. Talaśka, A. Ferreira, An Approach to Identifying Phenomena Accompanying Micro and Nanoparticles in Contact with Irregular Vessel Walls, IEEE Transactions on NanoBioscience 33(2016) 1241-1252.
[5] A.P. Chernyshev, The Ultra-Small Nanoparticles Physical Properties as a Reserve for New Technological Approaches, New Technological Materials 180 (2016) 39-42.
[6] M. Abhilash, Potential applications of Nanoparticles, international Pharma BioScience 1 (2010) 437-448.
[7] A.S. Teja, P.Y. Koh, Synthesis, properties, and applications of magnetic iron oxide nanoparticles, Progress in Crystal Growth and Characterization of Materials 55 (2009) 22-45.
[8] P. Majewski, B. Thierry, Functionalized Magnetite Nanoparticles—Synthesis, Properties, and Bio-Applications,Critical Reviews in Solid State and Materials Sciences 72 (2007) 203-215.
[9] S. Klotz, G.S. Neumann, Th. Strässle, J. Philippe, Th. Hansen, M.J. Wenzel, Magnetism and the Verwey transition in Fe3O4 under pressure, Physics Reviwe B 77 (2008) 670-674.
[10] M. Sarno, C. Cirillo, P. Ciambelli, Fluorescent and Magnetic Monodisperse Fe3O4 Nanoparticles, Chemical Engineering Transactions 43 (2015) 691-696.
[11] G.R. Chaudhary, P. Saharan, A. Kumar, S.K. Mehta, S. Mor. A. Umar, Adsorption Studies of Cationic, Anionic and Azo-Dyes via Monodispersed Fe3O4 Nanoparticles,Nanoscience and Nanotechnology 13 (2013) 3240-3245.
[12] F. Keyhanian, S. Shariati, M. Faraji, M. Hesabi, Magnetite nanoparticles with surface modification for removal of methyl violet from aqueous solutions, Arabian Journal of Chemistry 9 (2015) 348-354.
[13] J. Gao, W. Wei, M. J. Shi, H. Han, J. Lu, J. Xie, A controlled solvethermal approach to synthesize nanocrystalline iron oxide for congo red adsorptive removal from aqueous solutions, Material science 51 (2016) 4481-4494.
 
[14] A.R. Rahmani, M. Zarrabi, M.R. Samarghandi, A. Afkhami, H.R. Ghaffari, Degradation of Azo Dye Reactive Black 5 and Acid Orange 7 by Fenton-Like Mechanism, Iranian Journal of Chemical Engineering7 (2010) 87-94.
Journal of Research on Many-body Systems
Volume 9, Issue 3 - Serial Number 22
December 2019
Pages 16-28

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History

  • Receive Date: 01 July 2018
  • Revise Date: 07 June 2019
  • Accept Date: 07 July 2019

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