اثر نانوکامپوزیت اکسید گرافن/کبالت بر خواص رئولوژی سیال حفاری

قائمی, محبوبه; موسیوند, صبا; جوانمرد, کیوان

doi:10.22055/jrmbs.2023.18132

اثر نانوکامپوزیت اکسید گرافن/کبالت بر خواص رئولوژی سیال حفاری

نوع مقاله : مقاله پژوهشی کامل

نویسندگان

¹ گروه فیزیک، دانشکده علوم پایه، دانشگاه لرستان، خرم‌آباد، ایران

² گروه شیمی، دانشکده علوم پایه، دانشگاه لرستان، خرم‌آباد، ایران

10.22055/jrmbs.2023.18132

چکیده

نانوکامپوزیت اکسید گرافن/کبالت با روش الکترواکسیداسیون ساخته شد و مورد مشخصه‌یابی ساختاری و مغناطیسی قرار گرفت. سپس اثر نانوکامپوزیت تولید شده بر خواص رئولوژی دو نوع سیال حفاری محتوی بنتونیت و صمغ طبیعی بررسی شد. نانوکامپوزیت به‌دست آمده با استفاده از XRD، FT-IR، SEM و VSM مشخصه‌یابی شد. نتایج XRD تشکیل ساختار نانوکامپوزیت اکسیدگرافن/کبالت را تأیید کرد. تصاویر میکروسکوپ الکترونی روبشی نشان‌دهندة شکل پولکی نانوذرات کبالت است که بر روی صفحات اکسید گرافن جایگزیده شده‌اند. طبق نتایج حاصل از VSM، مغناطش اشباع emu/g 167.04، پسماند مغناطیسی emu/g 9.94 و میدان وادارندگی Oe 142.5 تعیین شد. به‌منظور بررسی اثر نانوکامپوزیت اکسید گرافن/کبالت بر خواص رئولوژی دو نوع سیال حاوی بنتونیت و صمغ طبیعی، 0.1، 0.3 و 0.5 گرم از این نانوکامپوزیت به‌سیالات حفاری افزوده شد و خواص رئولوژی آنها با استفاده از دستگاه ویسکومتر هشت سرعته در سه دمای 50،23 و70 درجة سانتیگراد مورد بررسی قرار گرفت. نانوکامپوزیت اکسیدگرافن/کبالت در نمونه‌های بنتونیتی باعث افزایش ویسکوزیتة ظاهری، ویسکوزیتة پلاستیک، نقطه واروی و استحکام ژله‌ای به‌ترتیب تا حدود مقادیرcp 108، cp17، lb/100ft²165 و lb/100ft²170 و در نمونه‌های صمغی باعث کاهش این پارامترها به‌ترتیب تا حدود مقادیر cp 70، cp32، lb/100ft²42 و lb/100ft²5 می‌شود.

کلیدواژه‌ها

موضوعات

شاخه‌های میان‌رشته‌ای

عنوان مقاله [English]

The effect of graphene Oxide/Cobalt nanocomposite on the Rheological properties of drilling fluid

نویسندگان [English]

Mahboobeh Ghaemi ¹
Saba Mosivand ¹
, Keivan Javanmard ²

¹ Department of Physics, Faculty of Basic Sciences, Lorestan University, Khorram-Abad, Iran

² Department of Chemistry,, Faculty of Basic Sciences,, Lorestan University,, Khorram Abad, Iran

چکیده [English]

Graphene oxide/cobalt nanocomposite was synthesized using the electrooxidation method and its structural and magnetic properties were specified. The effect of the produced nanocomposite on the rheological properties of drilling fluids containing bentonite and natural gum was investigated. The nanocomposite was characterized using XRD, FT-IR, SEM and VSM. XRD results confirmed the formation of graphene oxide/cobalt nanocomposite. The SEM images show the scaly shape of cobalt nanoparticles substituted on the graphene oxide sheets. Based on VSM results, the saturation magnetization, remance magnetization and coercive field were determined to be 167.04 emu/g, 9.94 emu/g, and 142.5 Oe, respectively. In order to investigate the effect of graphene oxide/cobalt nanocomposite on the rheological properties of two types of fluids containing bentonite and natural gum, 0.1, 0.3, and 0.5 gr of nanocomposite were added to drilling fluids and their rheological properties were measured using an eight-speed viscometer at three temperatures of 23^oC, 50^oC and 70^oC. Graphene oxide/cobalt nanocomposite in the bentonite samples increases the apparent viscosity, plastic viscosity, yield point, and gel strength up to 108 cp, 17 cp, 165 lb/100ft²,and 170 lb/100ft², respectively, anddecreases these parameters in the samples containing natural gum down to 70 cp, 32 cp, 42 lb/100ft²,and 5 lb/100ft², respectively.

کلیدواژه‌ها [English]

Graphene oxide/cobalt nanocomposite
Drilling fluid
Bentonite
Natural gum
Rheological properties

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