طراحی، شبیه‌سازی و ساخت سلول خورشیدی پروسکایتی بر پایه الکترود شفاف V2O5/Ag/WO3

نژاد زنگنه, مدینه; قاسمی, محسن; قریشی, سیدمحمدباقر

doi:10.22055/jrmbs.2023.18129

طراحی، شبیه‌سازی و ساخت سلول خورشیدی پروسکایتی بر پایه الکترود شفاف V2O5/Ag/WO3

نوع مقاله : مقاله پژوهشی کامل

نویسندگان

¹ گروه لیزر و فوتونیک، دانشکده فیزیک، دانشگاه کاشان، کاشان، ایران

² گروه فیزیک، دانشکده علوم، دانشگاه شهرکرد، شهرکرد، ایران

³ پژوهشکده فناوی نانو، دانشگاه شهرکرد، شهرکرد، ایران

10.22055/jrmbs.2023.18129

چکیده

در این پژوهش الکترود سه‌لایه‌ای V₂O₅/Ag/WO₃(VAW) به‌عنوان یک ساختار رسانای شفاف با استفاده از روش ماتریس مشخصه طراحی و ساختار بهینة آن تعیین می‌شود. سپس یک سلول خورشیدی پروسکایتی بر پایة الکترود سه لایه‌ای VAW با ساختارGlass/V₂O₅/Ag/WO₃/PEDOT:PSS/CH₃NH₃PbI₃/PCBM/Al در نظر گرفته می‌شود و با استفاده از فرمول‌بندی ماتریس انتقال، ویژگی‌های اپتیکی سلول خورشیدی پروسکایتی بررسی می‌شود. در ادامه نشان داده می‌شود که اثر تغییر ضخامت لایه WO₃ روی ویژگی‌های اپتیکی سه لایه‌ای VAW و سلول خورشیدی پروسکایتی بر پایة الکترود VAW چشمگیرتر از اثر تغییر ضخامت لایة دی الکتریک V₂O₅ است. مقدار بیشینة چگالی جریان مدار کوتاه mA/cm² 19.3 در سلول خورشیدی پروسکایتی، برای ضخامت لایه اکسید وانادیوم 40 نانومتر و ضخامت لایة اکسید تنگستن 55 نانومتر به‌دست آمد که از مقدار محاسبه شده برای سلول خورشیدی پروسکایتی با الکترود ITO (17.2 mA/cm² )، 12.2% بیشتر است. در نهایت سلول خورشیدی پروسکایتی بر پایة الکترود بهینه شده VAW ساخته شد و نتایج نشان دادند که این سلول خورشیدی کارآیی بهتری نسبت به سلول خورشیدی بر پایة الکترود تجاری ITO دارد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Design, simulation and fabrication of perovskite solar cell based on V2O5/Ag/WO3 transparent electrode

نویسندگان [English]

Madineh Nejadzangeneh ¹
Mohsen Ghasemi ² ³
Seyed Mohammad Bagher Ghorashi ¹

¹ Department of Laser and Photonics, Faculty of Physics, University of Kashan, Kashan, Iran

² Department of Physics, Faculty of Sciences, Shahrekord University, Shahrekord, Iran|Nanotechnology Research Institute, Shahrekord University, Shahrekord, Iran

³ Department of Physics, Faculty of Sciences, Shahrekord University, Shahrekord, Iran|Nanotechnology Research Institute, Shahrekord University, Shahrekord, Iran

چکیده [English]

In this research, using the characteristic matrix theory, the three-layer V₂O₅/Ag/WO₃ (VAW) electrode as a transparent conductive structure is designed and its optimal structure is determined. Then, a perovskite solar cell based on a VAW three-layer electrode with Glass/V₂O₅/Ag/WO₃/PEDOT:PSS/CH₃NH₃PbI₃/PCBM/Al structure is considered and the optical properties of the perovskite solar cell are investigated using the transfer matrix method (TMM). In the following, it is shown that the effects of changing the thickness of the WO₃ layer on the optical properties of the three-layer VAW and the perovskite solar cell based on the VAW electrode are more significant than the effects of changing the thickness of the layer V₂O₅. The maximum short circuit current density (19.3 mA/cm²) in the perovskite solar cell based on the VAW electrode was obtained for the thicknesses of the V₂O₅ layer of 40 nm and WO₃ layer of 55 nm, which is 12.2% higher than the calculated value for perovskite solar cell based on ITO electrode (17.2 mA/cm²). Finally, the perovskite solar cell based on the optimized VAW electrode was fabricated and the results showed that this solar cell has better performance than solar cell based on the commercial ITO electrode.

کلیدواژه‌ها [English]

Transparent conductive electrode
Dielectric/metal/dielectric
Perovskite solar cell. Simulation
Shortcut circuit current density

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